新书介绍-Gas Hydrates

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Gas Hydrates: From Characterization and Modeling to Applications

Daniel Broseta , Livio Ruffine ,  Desmedt Arnaud

ISBN:978-1-84821-969-4

302 pages

July 2017,   Wiley-ISTE

Description

Gas hydrates, orclathrate hydrates, are crystalline solids resembling ice, in which small(guest) molecules, typically gases, are trapped inside cavities formed byhydrogen-bonded water (host) molecules. They form and remain stable under lowtemperatures – often well below ambient conditions – and high pressures rangingfrom a few bar to hundreds of bar, depending on the guest molecule. Theirpresence is ubiquitous on Earth, in deep-marine sediments and in permafrostregions, as well as in outer space, on planets or comets. In addition to water,they can be synthesized with organic species as host molecules, resulting inmilder stability conditions: these are referred to as semi-clathrate hydrates.Clathrate and semi-clathrate hydrates are being considered for applications asdiverse as gas storage and separation, cold storage and transport and watertreatment.

This book is the first of twoedited volumes, with chapters on the experimental and modeling tools used forcharacterizing and predicting the unique molecular, thermodynamic and kineticproperties of gas hydrates (Volume 1) and on gas hydrates in their naturalenvironment and for potential industrial applications (Volume 2).

Table of Contents

1. Neutron Scattering ofClathrate and Semiclathrate Hydrates.

2. Spectroscopy of GasHydrates: From
 Fundamental Aspects toChemical Engineering, Geophysical and Astrophysical Applications.

3. High-Resolution OpticalMicroscopy
 of Gas Hydrates.

4. CalorimetricCharacterization of Clathrate and Semiclathrate Hydrates.

5. Thermodynamic Modeling ofSolid–Fluid
 Equilibria: From PureSolid Phases to Gas Semiclathrate Hydrates.

6. Volume and Non-EquilibriumCrystallization
 ofClathrate Hydrates.

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